Very first scene Olivia appeared in and probably pretty obvious why it is one of my favorites, I mean LOOK at her. She's gorgeous, adorable, sexy, and cute.
I love this scene because she puts her life first for once. Olivia is always so focused on the job and here she tells Broyles that she quits (for the weekend) to get for a moment away from all the crazy and I love that that side of her exists. Even though we don't get to see that side too often.